Silanes
Silanes
Silanes are organofunctional silicone monomers playing a critical role in bonding incompatible materials, specifically bridging the gap between inorganic substrates like glass, silica and metals and organic polymers. They function as coupling agents, adhesion promoters and surface modifiers.
| Grade | Chemical Name | Structural Formula | Molecular Weight | Specific Gravity @ 25°C | Refractive Index x @25°C | Flash Point, °C | Boiling Point, °C | Minimum coverage m2/g | List # | Applicable Resins |
|---|---|---|---|---|---|---|---|---|---|---|
| SC-13 | Vinyl trichlorosilane | CH2=CHSiCI3 | 161.5 | 1.26 | 1.432 | 9.0 | 91 | 480 | 2.2037 | Unsaturated polyesters |
| SC-23 | Vinyl tris (2-methoxyethoxy) silane | CH2=CHSi(OC2H4OCH3)3 | 280.4 | 1.04 | 1.427 | 146 | 285 | 278 | 2.2067 | Unsaturated polyesters |
| SC-33 | Vinyl triethoxysilane | CH2=CHSi (OC2H5)3 | 190.3 | 0.90 | 1.397 | 59 | 161 | 410 | 2.2066 | Crosslinked polyethylene |
| SC-43 | Vinyl trimethoxysilane | CH2=CHSi(OCH3)3 | 148.2 | 0.97 | 1.391 | 32 | 123 | 515 | 2.2066 | Crosslinked polyethylene |
| SC-35 | 3-Methacryloxy propyl trimethoxysilane |
CH3
|
CH2=C-C-O-C3H6Si(OCH3)3
⇓
O
|
248.4 | 1.04 | 1.429 | 125 | 255 | 314 | 2.2076 | Unsaturated polyesters |
| SC-38 | Ethylenetrimethoxy-silane | C2H4Si(OCH3)3 | 247.4 | 1.06 | 1.448 | 163 | 310 | 317 | 3.2647 | Epoxy, phenolic melamine |
| SC-48 | 3-Glycidyloxypropyl trimethoxysilane |
CH2--CHCH2OC3H6Si(OCH3)3
\ /
O
|
236.3 | 1.07 | 1.427 | 149 | 290 | 330 | 2.2071 | Epoxy, phenolic melamine |
| SC-42 | 3-Glycidyloxypropyl methyldiethoxysilane |
CH3
|
CH2--CHCH2OC3H6Si(OC2H5)2
\ /
O
|
248.4 | 0.98 | 1.431 | 128 | 259 | 356 | 2.2072 | Epoxy, phenolic, melamine |
| SC-36 | N-2-(Aminoethyl)-3-aminopropyl trimethoxysilane | H2NC2H2NHC3H6Si(OCH3)3 | 222.4 | 1.02 | 1.445 | 128 | 259 | 351 | 2.2083 | Epoxy, phenolic melamine |
| SC-26 | N-2-(Aminoethyl)-3-aminopropyl trimethoxysilane |
CH3
|
H2NC2H4NHC3H6Si(OCH3)2
|
206.4 | 0.97 | 1.445 | 110 | 234 | 380 | 2.2084 | Epoxy, phenolic melamine furan. |
| SC-39 | 3-Aminopropyl Triethoxysilane | H2NC3H6Si(OC2H5)3 | 221.4 | 0.94 | 1.420 | 98 | 217 | 353 | 2.2061 | Nylon, epoxy phenolic, melamine |
| SC-75 | N-Phenyl-3-aminopropyl trimethoxysilane | C6H5NHC3H6Si(OCH3)3 | 255.4 | 1.07 | 1.504 | 165 | 312 | 307 | 3.2644 | Polyimide epoxy phenolic melamine |
| SC-81 | 3-Mercaptopropyl trimethoxysilane | HSC3H6Si(OCH3)3 | 196.4 | 1.06 | 1.440 | 99 | 219 | 398 | 2.2045 | Rubbers |
| SC-17 | 3-Chloropropyl trimethoxysilane | ClC3H6Si(OCH3)3 | 198.7 | 1.08 | 1.418 | 83 | 196 | 393 | 2.2079 | Epoxy |
Silanes Applications
Silanes are first categorized by their primary function – coupling agents or crosslinking agents – and secondly by their specific molecular functional groups.
| Chemical Group | Functionality and Use | Applications |
|---|---|---|
|
Aminosilanes (SC-26, SC-36, SC-39, SC-75) |
Adhesion Promotion | Bonding on glass, metal, ceramics |
| Industrial Fillers |
Glass fiber reinforcement Used in mineral filler treatments Pigment dispersion |
|
| Compatibility | Polyurethane, phenolic, epoxy resins | |
| Use |
Composites, molding, electronics encapsulants, automotive sealants |
|
|
Vinylsilanes (SC-13, SC-23, SC-33, SC-43) |
Polymerization/Crosslinking | Thermoplastics Modifiers |
| Mechanical Reinforcement | Increased strength and flexibility of plastics and rubbers | |
| Use |
Plastic packaging, heat resistant pipes, aerospace parts, high voltage cables |
|
|
Epoxysilanes (SC-42, SC-48) |
Chemical and thermal resistance | Compatiblity to epoxy, polyurethane, acrylic resins |
| Use |
Heavy-duty adhesives, protective paints, water Resistant industrial coatings, electronics packaging |
|
|
Alkoxy & Chlorosilanes (SC-17, SC-37, SC-38) |
Silylation | Chemical manufacturing of intermediates |
| Surface Modification | Rendering hydrophobicity to substrates | |
| Use |
Water repellant treatments Moisture scavangers Chemical synthesis reagents |
|
|
Mercaptosilanes (SC-81) |
Elastomer coupling | Create strong bonds of silica fillers and natural or synthetic rubbers |
| Enhancement of physical properties | Increase tearing resistance and flexibility of compounds under high dynamic stress | |
| Use |
Industrial gaskets, mechanical seals, automotive belts, high performance tire treads |
|
|
Metacryloxy silanes (SC-35) |
Reactive curable agent for UV and Acrylic systems |
Specifically made for acrylic pressure-sensitive adhesives, radiation-cured inks and light-curable systems |
| Use |
Dental composites, adhesives, industrial coatings, artificial stones |